Question #61318

Timothy has 1 gallon of 6% bleach, assume 94% is water. Timothy decides to dilute the bleach separately. Timothy pours 10mL+0.1, 9mL+0.1, 8mL+0.1, 7mL+0.1, 6mL+0.1, and 1mL+0.1, of the bleach into 6 different containers and then fills the difference to 10mL with water. The density of the bleach is 1.11 g/cm3, and the 10mL is measured in a graduated cylinder. Calculate the new concentration, in moles per decimeter cubed, of the bleach in each container.
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Expert's answer

2016-08-22T13:10:03-0400

Answer on Question#61318 – Chemistry – General chemistry

Answer: Timothy has 1 gallon of 6% bleach, assume 94% is water. Timothy decides to dilute the bleach separately. Timothy pours 10mL+0.1, 9mL+0.1, 8mL+0.1, 7mL+0.1, 6mL+0.1, and 1mL+0.1, of the bleach into 6 different containers and then fills the difference to 10mL with water. The density of the bleach is 1.11 g/cm³, and the 10mL is measured in a graduated cylinder. Calculate the new concentration, in moles per decimeter cubed, of the bleach in each container.

Solution:

The chemical formula of bleach is NaClO. M(NaClO) = 74.5 g/mol

1 gallon = 378.412 dm³ = 378412 cm³

m(bleach) = 378412 cm³ · 1.11 g/ml = 420037.32 g

m(NaClO without water) = 420037.32 g · 0.06 = 25202.24 g

n(NaClO) = 25202.24 g74.5 g/mol=338.29 mol\frac{25202.24\ g}{74.5\ g/mol} = 338.29\ mol;

C0(NaClO)=338.29 mol378.412 dm3=0.894 mol/ dm3C_0(\mathrm{NaClO}) = \frac{338.29\ mol}{378.412\ dm^3} = 0.894\ \mathrm{mol}/\ \mathrm{dm}^3;

Cnew=C0V0VnewC_{\text{new}} = \frac{C_0 V_0}{V_{\text{new}}}, Error(%) = 0.1V0100%\frac{0.1}{V_0} \cdot 100\%;

Error(mol/dm³) = Error(%)Cnew100\frac{\text{Error}(\%) \cdot C_{\text{new}}}{100}


Answer:



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