Give an example of
a) an endothermic process that is spontaneous
b) an exothermic process that is spontaneous
c) a reversible process
d) an irreversible process
Solution:
a) an endothermic process that is spontaneous
The reaction of baking soda (NaHCO3) with vinegar (CH3COOH) is endothermic
NaHCO3(s) + CH3COOH(aq) → CH3COONa(aq) + H2O(l) + CO2(g), ΔH°rxn = +2945.2 kJ
b) an exothermic process that is spontaneous
The oxidation of sulfur dioxide (SO2) by oxygen gas (O2) to sulfur trioxide (SO3) is an exothermic reaction
2SO2(g) + O2(g) → 2SO3(g), ΔH°rxn = −198.2 kJ
c) a reversible process
The reaction of hydrogen gas (H2) with iodine gas (I2) gives hydrogen iodide (HI) – a reversible reaction
H2(g) + I2(g)  ⇆ 2HI(g)
d) an irreversible process
The reaction of sodium (Na) with water (H2O) is an irreversible process
2Na(s) + H2O(l) → 2NaOH(aq) + H2(g)
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