The safety air bags in automobiles are inflated by nitrogen gas generated by the rapid decomposition of sodium azide, NaN3 (molar mass= 65.01 g/mol). If an air bag has a volume of 36 L and is to be filled with nitrogen gas at a pressure of 1.15 atm at a temperature of 26.0 °C, how many grams of NaN3 must be decomposed? _____ g NaN3
The reaction of azide decomposition:
"2NaN_3\u21922Na+3N_2"
The mole number can be deduced from the given parameters:
"pV=nRT" ,
where p is a pressure in atm, V is the volume in litres (L), n is a mole number, R is a gas constant ("0.082 \\frac{L\\times atm}{R \\times mole}" ) and T is the temperature in Kelvin.
"n=\\frac{pV}{RT} = \\frac{1.15 atm \\times 36 L}{0.082 \\times (26+273)K} = 1.69 mole"
The mass of azide can be obtained from mole number:
"m = nM = 1.69 mole \\times 65.01 g\/mol = 109.78 g"
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