How much heat is evolved when 1249 g of water condenses to a liquid at 100.°C?
n(H2O) = m(H2O) / Mr(H2O)
n(H2O) = 1249 g / 18 g/mol = 69.4 moles
∆𝐻𝑣𝑎𝑝 = −∆𝐻𝑐𝑜𝑛𝑑
The molar heat of vaporization of water is ∆𝐻𝑣𝑎𝑝 = 40.7𝑘𝐽 𝑚𝑜𝑙
∆𝐻 =69.4 𝑚𝑜𝑙 𝐻2𝑂∙ (−40.7𝑘𝐽/1𝑚𝑜𝑙 𝐻2𝑂) = - 2824.6 𝑘𝐽
The negative sign indicate that heat is given off.
Therefore, the process will release 2824.6 𝒌𝑱 of heat.
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