If 3.2443 moles of carbon dioxide are produced, how many grams of iron (III) oxalate were reacted if the reaction proceeds with a 99.6% yield?
Solution:
carbon dioxide = CO2
iron(III) oxalate = Fe2(C2O4)3
Assume that the reaction is the decomposition of iron(III) oxalate
Then, the balanced chemical equation is:
Fe2(C2O4)3 → 2FeC2O4 + 2CO2
According to stoichiometry:
1 mol of Fe2(C2O4)3 produces 2 mol of CO2
X mol of Fe2(C2O4)3 produces 3.2443 mol of CO2
Thus,
Moles of Fe2(C2O4)3 = X = (3.2443 mol CO2) × (1 mol Fe2(C2O4)3 / 2 mol CO2) = 1.62215 mol Fe2(C2O4)3
Given the yield of the reaction:
Moles of Fe2(C2O4)3 = (1.62215 mol × 100%) / (99.6%) = 1.628665 mol
The molar mass of Fe2(C2O4)3 is 375.747 g mol−1
Therefore,
Mass of Fe2(C2O4)3 = (1.628665 mol) × (375.747 g mol−1) = 611.966 g
Mass of Fe2(C2O4)3 = 611.966 g
Answer: 611.966 grams of iron(III) oxalate were reacted
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