The initial rate data for the reaction 2N2O5(g) → 4NO2(g) + O2(g) is shown in the following table.
Experiment [N2O5](M) Rate (M/s)
1 1.28 × 102 22.5
2 2.56 x 102 45.0
a. Determine the order of reaction of the given reactant.
b. Determine the value of the rate constant for this reaction.
(a) rate law expression can be given as follows
"rate=k[N_2O_5]^a ......................(i)"
"22.5=k[1.28\\times 10^2]^a ......................(i)"
"45=k[2.56\\times 10^2]^a ......................(ii)"
dividing (ii) by (i)
"2=[2]^a"
On compairing both
value of a is 1
order of reaction
for finding rate constant use equation 1
(b)
"45=k[2.56\\times 10^2]^1"
"k= 17.578 \\times 10^{-2} s^{-1}"
"k= 1.76 \\times 10^{-1} s^{-1}"
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