Consider the reaction below
I2O5(g) + 5 CO2(g) ———> 5 CO2(g) + I2(g)
80.0g of iodine (v) oxide reacts with 28.0g of carbon monoxide. Determine the mass of iodine I2 which would be produced
Solution:
The molar mass of iodine(V) oxide (I2O5) is 333.81 g/mol
The molar mass of carbon monoxide (CO) is 28.01 g/mol
Calculate moles of each reactant:
Moles of I2O5 = (80.0 g I2O5) × (1 mol I2O5 / 333.81 g I2O5) = 0.23966 mol I2O5
Moles of CO = (28.0 g CO) × (1 mol CO / 28.01 g CO) = 0.99964 mol CO
Balanced chemical equation:
I2O5(g) + 5CO(g) ⟶ 5CO2(g) + I2(g)
According to stoichiometry:
1 mol of I2O5 reacts with 5 mol of CO
Thus, 0.23966 mol I2O5 reacts with:
(0.23966 mol I2O5) × (5 mol CO / 1 mol I2O5) = 1.1983 mol CO
However, initially there is 0.99964 mol of CO (according to the task).
Therefore, CO acts as limiting reactant and I2O5 is excess reactant.
According to stoichiometry:
5 mol of CO produces 1 mol of I2
Thus, 0.99964 mol of CO produces:
( 0.99964 mol CO) × (1 mol I2 / 5 mol CO) = 0.19993 mol I2
The molar mass of iodine (I2) is 253.809 g/mol
Therefore,
Mass of I2 = (0.19993 mol I2) × (253.809 g I2 / 1 mol I2) = 50.744 g I2 = 50.7 g I2
Mass of I2 = 50.7 g
Answer: 50.7 grams of iodine (I2) would be produced
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