169cm^3 of hydrogen were collected over water at 20°c and 755 mmHg. The saturated vapour pressure of water at 20°c is 17 .5 mmHg. What will be the volume of the hydrogen at s.t.p
Volume of hydrogen = 169 cm3 =V1, Temperature of hydrogen gas collected = 20oC= T1, Pressure of gas = 755 = P1
At stp , Temperature = 25oC=T2 and Pressure = P2= 760 mm Hg
Using ideal gas equation
"\\frac{P_1V_1}{T_1}=\\frac{P_2V_2}{T_2}"
"\\frac{755\u00d7169}{293}=\\frac{760\u00d7V_2}{298}"
"V_2= 170.7 cm^3"
Volume of gas at STP is =170.7 cm3
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