a. Formic acid, which is a component of insect venom, has a Ka = 1.8 x 10-4. What is the [H3O+] in a solution that is initially 0.20 M formic acid, HCOOH? (4 pts.)
HCOOH(aq) + H2O(l) ⇌ H3O+(aq) + HCOO–(aq)
(acid-base equilibria)
Answer is: concentration of H₃O⁺ ions is 4.2·10⁻³ M.
Chemical reaction: HCOOH(aq) + H₂O(l) ⇄ HCOO⁻(aq) + H₃O⁺(aq).
c(HCOOH) = 0,1 M.
[H₃O⁺] = [HCOO⁻] = x.
[HCOOH] = 0,1 M - x.
Ka = [H₃O⁺] · [HCOO⁻] / [HCOOH].
0,00018 = x² / (0,1 M - x).
Solve quadratic equation: x = [H₃O⁺] = 0,0042 M.
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