if 25cm3 of a soltuion of NaOH are neutralised by 27.5cm3 of H2SO4 of a concentration of 0.250moldm-3 what is the concentration of the NaOH?
Balanced chemical equation for the reaction:
2NaOH + H2SO4 products Na2SO4 + 2H2O
Provided data:
NaOH; volume - 25cm3 = 0.025dm3
H2SO4; volume - 27.5cm3 = 0.0275dm3
concentration - 0.250moldm-3
n (moles of H2SO4) = 0.250mol/dm3 H2SO4 × 0.0275dm3 H2SO4 (dm3 cancels out).
= 6.875 × 10-3 moles H2SO4
From the balanced equation,
Mole ratio of NaOH : H2SO4 is 2:1
Therefore,
6.875 × 10-3 moles H2SO4 × 2 moles NaOH/1 moles H2SO4
= 1.375 × 10-2 moles NaOH
n=1.375 × 10-2 moles, V= 0.025 dm3
C= 1.375 × 10-2 moles/0.025 dm3 = 0.55 moldm-3
Therefore, concentration of NaOH is 0.55 moldm-3
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