Consider the reaction PCl3(g) + Cl2(g) ⇋ PCl5(g) Kc = 0.040 at 450oC. If a reaction is initiated with 0.40 mole of Cl2 and 0.40 mole of PCl3 in a 2.0 liter container, what is the equilibrium concentration of PCl5 in the same system?
"K \n\nc\n\n\u200b\t\n\n =20= \n\n\\frac{(0.4+x)}{(0.2\u2212x)(0.3\u2212x)}"
"20= \n\n\\frac{0.4+x}{0.06\u22120.5x+x \n\n^2}"
∴20x2 −11x+0.8=0
∴x=0.08
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