Freon – 12, CCl2F2, is prepared from CCl4 by reaction with HF. The other product of this reaction is HCl. Outline the steps needed to determine the percent yield of a reaction that produces 12.5 g of CCl2F2 from 32.9 g of CCl4. Freon – 12 has been banned and is no longer used as a refrigerant because it catalyzes the decomposition of ozone and has a very long lifetime in the atmosphere. Determine the percent yield.
CCl4 + 2HF → CCl2F2 + 2HCl
m(CCl4) = 32.9 g
m’(CCl2F2) = 12.5 g
M(CCl4) = 153.82 g/mol
n(CCl4) "= \\frac{32.9}{153.82} = 0.2138 \\;mol"
n(CCl2F2) = n(CCl4) = 0.2138 mol
M(CCl2F2) = 120.91 g/mol
m(CCl2F2) "= 0.2138 \\times 120.91 = 25.85 \\;g"
Proportion:
25.85 g – 100 %
12.5 g – x
"x = \\frac{12.5 \\times 100}{28.85} = 43.32" %
The percent yield = 43.32 %.
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