4NH3 + 5O2 → 4NO + 6H2O (1)
2NO + O2 → 2NO2 (2)
3NO2 + H2O → 2HNO3 + NO (3)
M(HNO3) = 63.01 g/mol
n(HNO3) =Mm=63.011000=15.87mol
According to the reaction (3):
n(NO2) = 23 n(HNO3) =23×15.87=23.80mol
According to the reaction (2):
n(NO) = n(NO2) = 23.80 mol
According to the reaction (1):
n(O2) = 45 n(NO) =45×23.80=29.75mol
M(O2) = 15.99 g/mol
m(O2) =15.99×29.75=475.70g
Answer: 475.70 g
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