A sample of nitrogen gas expands in volume from 1.6 L to 5.4 L at constant temperature. Calculate the work done in joules if the gas expands (a) against a vacuum, (b) against a constant pressure of 0.80 atm, and (c) against a constant pressure of 3.7 atm.
Solution
a.) W=−0×(5.4−1.6)L=0W = -0 ×(5.4-1.6) L = 0W=−0×(5.4−1.6)L=0 J
b.) P=0.80P = 0.80P=0.80
V2−V1=(5.4−1.6)=3.8LV2-V1 = ( 5.4-1.6) = 3.8 LV2−V1=(5.4−1.6)=3.8L
1L.atm=101.325J1 L.atm = 101.325 J1L.atm=101.325J
W=−0.80×3.8=−3.04W= - 0.80×3.8 = -3.04W=−0.80×3.8=−3.04
=−3.04×101.325J=−308.03J= -3.04×101.325 J = -308.03 J=−3.04×101.325J=−308.03J
c.)P=3.7atmP = 3.7 atmP=3.7atm
W=−3.7×3.8=−14.06L.atmW = - 3.7×3.8 = -14.06 L.atmW=−3.7×3.8=−14.06L.atm
=−14.06×101.325J-14.06×101.325 J−14.06×101.325J
=−1424.63J= -1424.63 J=−1424.63J
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