A sample of nitrogen gas expands in volume from 1.6 L to 5.4 L at constant temperature. Calculate the work done in joules if the gas expands (a) against a vacuum, (b) against a constant pressure of 0.80 atm, and (c) against a constant pressure of 3.7 atm.
Solution
a.) "W = -0 \u00d7(5.4-1.6) L = 0" J
b.) "P = 0.80"
"V2-V1 = ( 5.4-1.6) = 3.8 L"
"1 L.atm = 101.325 J"
"W= - 0.80\u00d73.8 = -3.04"
"= -3.04\u00d7101.325 J\n\n\n\n = -308.03 J"
c.)"P = 3.7 atm"
"V2-V1 = ( 5.4-1.6) = 3.8 L"
"W = - 3.7\u00d73.8 = -14.06 L.atm"
="-14.06\u00d7101.325 J"
"= -1424.63 J"
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