Xenon crystallizes in a FCC unit cell. If we assume xenon has a radius of 186.9 pm, what is the density of xenon in g/cm3 ?
Number of atoms present in a FCC unit are four.
Density of face-centered cubic unit cell=4×MA3×Na\frac{4\times M}{A3\times Na}A3×Na4×M
M=molar mass of xenon=131.293gM=molar\space mass \space of \space xenon=131.293gM=molar mass of xenon=131.293g
A=A=A= edge of unit cell=22r=2×2×186.9×10−12=3.8668×10−3cm=2\sqrt{2r}=2\times \sqrt{2\times 186.9\times 10^{-12}}=3.8668\times 10^{-3}cm=22r=2×2×186.9×10−12=3.8668×10−3cm
Na=Na=Na= Avogadro's number=6.02×1023=6.02\times 10^{23}=6.02×1023
In this case, density of xenon=4×131.293g(3.8668×10−3)3×6.02×1023cm3=525.172g(3.4806×1016cm3)=1.5089×10−14g/cm3=\frac{4\times 131.293g}{(3.8668\times 10^{-3})^3 \times 6.02\times 10^{23}cm^3}=\frac{525.172g}{(3.4806\times 10^{16}cm^3)}=1.5089\times 10^{-14}g/cm^3=(3.8668×10−3)3×6.02×1023cm34×131.293g=(3.4806×1016cm3)525.172g=1.5089×10−14g/cm3
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