Balance the following reactions using the given method:
1."MnO_ \n4^\n\u2212\n\u200b\t\n =2,C _\n2\n\u200b\t\n O \n_4\n^{2\u2212} \n\u200b\t\n =5,H \n^+\n =16"
2.Zn + NO3- = Zn(OH)42- + NH3 (oxidation method - basic solution)
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