Question #181304

Solve the given problem


 3 HCI + AI(OH)3 --> 3 H2O AICI3

1) How many grams og aluminum hydroxide will react 5.3 moles of HCI?


 2 NaOH + H2SO4 --> 2 H20 + Na2SO4

2) How many grams of solution of sofium sulfatr will be formed, if you start with 1.25 L of a 4.0 M solution of sodium hydroxide?


1
Expert's answer
2021-04-19T05:14:10-0400

Q181304

Solve the given problem



Question 1


 3 HCI + AI(OH)3 --> 3 H2O + AICI3

How many grams of aluminum hydroxide will react 5.3 moles of HCI?


 Solution :


In the given reaction the mol to mol ratio of HCl and Al(OH)3 is 3 :1 .

Using this ratio find the moles of Al(OH)3 that will react with 5.3 moles of HCl .



mol of AlCl3=5.3 mol HCl1 mol Al(OH)33 mol HCl=1.77 mol Al(OH)3mol \ of \ AlCl_3 = 5.3 \ mol \ HCl * \frac{1 \ mol \ Al(OH)_3}{3 \ mol \ HCl } = 1.77 \ mol \ Al(OH)_3


Next convert 1.77 mol Al(OH)3 to grams by using molar mass of Al(OH)3.


molar mass of Al(OH)3 = 1 * atomic mass of Al + 3 * atomic mass of O + 3 * atomic mass of H.

= 1 * 26.982 g/mol + 3 * 15.999 g/mol + 3 * 1.00794 g/mol

= 78.0028 g/mol


Using molar mass 78.0028 g/mol convert 1.77 mol Al(OH)3 to grams.



grams of Al(OH)3=1.77 mol Al(OH)3 78.0028 g Al(OH)31 mol Al(OH)3grams \ of \ Al(OH)_3 = 1.77 \ mol \ Al(OH)3 \ * \frac{78.0028 \ g \ Al(OH)_3 }{1 \ mol \ Al(OH)_3 }

=138.06 grams of Al(OH)3= 138.06\ grams \ of \ Al(OH)_3

In question we are given 5.3 mole HCl in 2 significant figure, so our final answer must also be in

2 significant figure.



Hence the mass of Al(OH)3 that will react with 5.3 mole HCl is 140 grams.


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Question 2


  2 NaOH + H2SO4 --> 2 H20 + Na2SO4


How many grams of solution of sodium sulfate will be formed, if you start with 1.25 L of a 4.0 M solution of sodium hydroxide?


Solution :


Step 1 : To find the moles of NaOH present in 1.25 L of 4.0 M solution.


Let us first find the moles of NaOH present in 1.25 L of 4.0 M solution of sodium hydroxide.


Plug volume = 1.25 L and molarity = 4.0 M in the molarity formula and find the

moles of NaOH.



Molarity=moles of NaOHvolume of solution in LMolarity = \frac{moles \ of \ NaOH }{volume \ of \ solution \ in \ 'L' }

4.0M=moles of NaOH1.25 L4.0M = \frac{moles \ of \ NaOH }{1.25 \ L }

Arranging the equation for ' moles of NaOH' , we have



moles of NaOH = 4.0 mol/L1.25 L = 5.0 moles of NaOH.moles \ of \ NaOH \ = \ 4.0 \ mol/L * {1.25 \ L } \ = \ 5.0 \ moles \ of \ NaOH.


Step 2 : To find the moles of Na2SO4 that is formed from 5.0 moles of NaOH.


The reaction of NaOH and H2SO4 is


2 NaOH + H2SO4 --> 2 H20 + 1 Na2SO4


The mol to mol ratio of NaOH and Na2SO4 in this reaction is 2 mol NaOH : 1 mol Na2SO4.

Using this ratio find the moles of Na2SO4 that will be formed from 5.0 moles of NaOH.



moles of Na2SO4=5.0 mol of NaOH1 mol Na2SO42 mol NaOHmoles \ of \ Na_2SO_4 = 5.0 \ mol \ of \ NaOH * \frac{1 \ mol \ Na_2SO_4}{2 \ mol \ NaOH }

=2.5 mol Na2SO4= 2.5 \ mol \ Na_2SO_4

Step 3 : Convert 2.5 mol Na2SO4 to grams by using molar mass of Na2SO4.


molar mass of Na2SO4 = 2 * atomic mass of Na + 1 * atomic mass of S + 4 * atomic mass of O

= 2 * 22.99 g/mol + 1 * 32.065 g/mol + 4 * 15.999 g/mol

= 142.041 g/mol


Using molar mass 142.041 g/mol convert 2.5 moles of Na2SO4 to grams.



gramsofNa2SO4=2.5 mol Na2SO4142.041 g of Na2SO41 mol of Na2SO4grams of Na_2SO_4 = 2.5 \ mol \ Na_2SO_4 * \frac{142.041 \ g \ of \ Na_2SO_4 }{1 \ mol \ of \ Na_2SO_4}

=355.1 grams of Na2SO4= 355.1 \ grams \ of \ Na_2SO_4


In correct significant figure the answer will be 360 grams of Na2SO4.

The molarity given in the question is in 2 significant figure ( which is least)

So our final answer must also be in 2 significant figure.


Hence 360 grams of Na2SO4 will be formed from the given 1.25 L of a 4.0 M solution of sodium hydroxide




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