Solution.
1."N=3.011\\sdot 10^{23};"
"M(Au)=197g\/mol;"
"m_-?;"
"\\nu=\\dfrac{N}{N_A};"
"\\nu=\\dfrac{3.011\\sdot10^{23}}{6.02\\sdot10^{23}mol^{-1}}=0.5mol;"
"\\nu=\\dfrac{m}{M}\\implies m=\\nu M;"
"m=0.5mol\\sdot197g\/mol=98.5g."
2."m=15.0g;"
"M(CaSO_4)=136gmol^{-1};"
"N-?;"
"\\nu=\\dfrac{m}{M}=\\dfrac{N}{N_A}\\implies N=\\dfrac{mN_A}{M};"
"N=\\dfrac{15.0g\\sdot 6.02\\sdot 10^{23}mol^{-1}}{136gmol^{-1}}=6.64\\sdot10^{22}."
3."m=168.0g;"
"M(HgS)=232.6gmol^{-1};"
"\\nu-?;"
"\\nu=\\dfrac{m}{M};"
"\\nu=\\dfrac{168.0g}{232.6gmol^{-1}}=0.72mol;"
4."\\nu(H_2)=2mol;"
"\\nu(CH_4)=2mol;"
"\\nu=\\dfrac{m}{M}=\\dfrac{N}{N_A}\\implies N=\\dfrac{mN_A}{M}=\\nu N_A;"
"N(H_2)=2mol\\sdot6.02\\sdot10^{23}mol^{-1}=12.04\\sdot10^{23};"
"N(CH_4)=2mol\\sdot6.02\\sdot10^{23}mol^{-1}=12.04\\sdot10^{23};"
5."\\nu(H_2)=2mol;"
"\\nu(CH_4)=2mol;"
"M(H_2)=2gmol^{-1};"
"M(CH_4)=16gmol^{-1};"
"\\nu=\\dfrac{m}{M}\\implies m=\\nu M;"
"m(H_2)=2mol\\sdot2gmol^{-1}=4g;"
"m(CH_4)=2mol\\sdot16gmol^{-1}=32g;"
Answer: "1." "m=98.5g;"
"2." "N=6.64\\sdot10^{22};"
"3." "\\nu=0.72mol;"
"4." "N(H_2)=12.04\\sdot10^{23}; N(CH_4)=12.04\\sdot10^{23};"
"5." "m(H_2)=4g;m(CH_4)=32g."
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