Question #152806

Calculate the time required to deposit 0.37g of Silver from a silver Nitrate solution using a current of 2.5A ( Charge of Ag in is AgNO 3 is +1)


1
Expert's answer
2020-12-28T04:41:11-0500

If Farade constant = 96485 Cmol-1

Atomic mass of Ag = 107.5 gmol-1


  • Deposition occurs as,

Ag+(aq) + e ------> Ag(s) ---- (1)


  • No of Ag moles deposited ( nAg ) = 0.37g107.5gmol1\dfrac{0.37g}{107.5gmol^{-1}}

= 3.44×103mol3.44\times10^{-3} mol


  • As per the equation (1),

ne=nAgn_e = n_{Ag}\\

  • Using,

Q=It,3.44×103mol  ×  96485  Cmol1  =  2.5A  ×  tt  =  132.76sQ =It,\\3.44\times10^{-3}mol\;\times \;96485\; Cmol^{-1}\;=\;2.5A\;\times\;t\\ t\;=\;\bf132.76s




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