Question #151103
A scientist measures the standard enthalpy change for the following reaction to be -574.9 kJ:

H2CO(g) + O2(g)CO2(g) + H2O(l)

Based on this value and the standard enthalpies of formation for the other substances, the standard enthalpy of formation of H2O(l) is
1
Expert's answer
2020-12-14T14:50:31-0500

H2CO(g)+O2(g)CO2(g)+H2O(l)H 2 ​ CO(g)+O 2 ​ (g)→CO 2 ​ (g)+H 2 ​ O(l)

ΔHrxn=ΔHf0(products)ΔHf0(reactants)ΔH rxn ​ =∑ΔH f 0 ​ (products)−∑ΔH f 0 ​ (reactants)

ΔHf0(H2CO(g))=116kJmol\Delta H^0_f(H_2CO(g)) = -116 \frac{kJ}{mol} ​

ΔHf0(CO2(g))=393.5kJ/molΔH f 0 ​ (CO 2 ​ (g))=-393.5 kJ/mol

574.9KJ=[1×ΔHf0(H2O(l))+1×(393.5kJ/mol)][1×(116)+1×0]-574.9KJ=[1×ΔH f 0 ​ (H2O(l))+1×(-393.5 kJ/mol)]−[1×(−116)+1×0]

ΔHf0(H2O(l)=297.4KJΔH f 0 ​ (H2O(l)=297.4KJ


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