pH= 2.122.
[H+] = 0.00755092227665 M.
Ka=a^2 x C.
a=√(Ka/C) = √(4.0 x 10-5/0.00755092227665) = 0,0727830072
0.00755092227665/0,0727830072 =0,0727830072 M.
Cm=n/V. n= Cm x V= 0,0727830072 x 0.035 = 0,00363109866 moles.
Mr=m/n=8.42/0,00363109866=2 318,8574 / 100 = 23,188574
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