We know the formula,
r1/r2 = √(M2/M1)
Where, r1 = rate of diffusion of gas with molar mass M1.
r2 = rate of diffusion of gas with molar mass M2.
So, r ∝ 1/√M
i.e. rate of diffusion ∝ 1/√ molar mass
a) Molar mass of F2 = 38 g/mol
Molar mass of Cl2 = 71 g/mol
Molar mass of N2 = 28 g/mol
Molar mass of O2 = 32 g/mol
Decreasing order of Molar mass of the gases are,
Cl2>F2>O2>N2
As,
rate of diffusion ∝ 1/√ molar mass
So, rate of diffusion follow the order,
Cl2<F2<O2<N2
b)Molar mass of HCl = 36.5 g/mol
Molar mass of NH3 = 17 g/mol
Molar mass of NO = 30 g/mol
Molar mass of Kr = 84 g/mol
Decreasing order of Molar mass of the gases are,
Kr>HCl>NO>NH3
As,
rate of diffusion ∝ 1/√ molar mass
So, rate of diffusion follow the order,
NH3<NO<HCl<Kr
C) Molar mass of N2O = 44 g/mol
Molar mass of CO = 28 g/mol
Molar mass of Ne = 10 g/mol
Molar mass of O3 = 48 g/mol
Decreasing order of Molar mass of the gases are,
O3>N2O>CO>Ne
As,
rate of diffusion ∝ 1/√ molar mass
So, rate of diffusion follow the order,
O3<N2O<CO<Ne
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