A net ionic equation double replacement reaction in aqueous solution. It removes the spectator ions from the total equation to only list the species that participate in the reaction.
Let's look at this equation here.
HClO4 (aq)+NaOH(aq)⟶H2O(l)+NaClO4 (aq)
Writing these species as whole ionic compounds is a formality; in aqueous solution HClO4 will dissolve to form H+ and ClO4-. Similarly NaOH will dissolve to form Na+ and OH-. Since the salt formed NaClO4 is soluble in water, we'll write (aq) after it and we can say it's still dissolved in water as Na+ and ClO4-.
Substituting all of that in, let's expand out our equation:
HClO4 (aq)+NaOH (aq)⟶ H2O(l)+NaClO4 (aq)
H+(aq) + ClO4-(aq) + Na+(aq) + OH-(aq) ⟶ H2O (l) + Na+(aq) + ClO4-(aq)
We now can cancel out all the terms that are on both the left and the the right side of the equation. We call those spectator ions since they don't participate in the reaction.
H+(aq) + ClO4-(aq) + Na+(aq) + OH- (aq) ⟶ H2O (l) + Na+(aq) + ClO4-(aq)
We are left with the net ionic equation:
H+(aq) + OH- (aq) ⟶ H2O (l)
For any reaction between a strong acid and a strong base, the net ionic equation is the neutralization of H+(aq) + OH-(aq) to form water.
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