Question #137904

A 60.0L tank of chlorine gas at 27°C and 125atm springs a leak. When the leak was discovered, the pressure was reduced to 50atm. How many moles of chlorine gas escaped?

Expert's answer

Let's solve the Clapeyron-Mendeleev equation by equation:

P1V=n1RTP1V=n1RT

P2V=n2RTP2V=n2RT

(P1P2)V=(n1n2)RT(P1-P2)V=(n1-n2)RT

ΔPV=ΔnRT\Delta PV=\Delta nRT

Δn=ΔPVRT\Delta n=\frac{\Delta PV}{RT}

Δn=ΔPVRT=(12550)600.082300=450024.6=182.93\Delta n=\frac{\Delta PV}{RT}=\frac{(125-50)60}{0.082*300}=\frac{4500}{24.6}=182.93 mol


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