Question #133650

what is The pH and pOH of a 1.00x10-3M solution of CH3COOH (Ka=1.75x10-5) ?

Expert's answer

Solution:

CH3COOH=CH3COO+H+CH_{3}COOH=CH_{3}COO^{-}+H^{+}


Ka=1.75105K_{a}=1.75*10^{-5} so this equilibrium lies mostly to the left and there is no need for ICE tables. Under these conditions the equilibrium expression simplifies to 


[H+]=KaCM[H^{+}]= \sqrt{\smash[b]{K_{a}*C_{M}}}


[H+]=(1.75105)(103)[H^{+}]= \sqrt{\smash[b]{(1.75*10^{-5})*(10^{-3})}}


[H+]=[H^{+}]= 1.32104M1.32*10^{-4} M



pH=log(1.32104)pH=-log(1.32*10^{-4})


pH=3.88pH=3.88


pOH=14pH=10.12pOH=14-pH=10.12



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