Consider the reaction
CO(g)+NH3(g)⇌HCONH2(g), Kc=0.640
If a reaction vessel initially contains only CO and NH3 at concentrations of 1.00 M and 2.00 M, respectively, what will the concentration of HCONH2 be at equilibrium?
Solution:
According to given reaction, we can make a table of concentrations for each compounds:
CO(g)+NH3(g)⇌HCONH2(g)
Unitial 1.00 2.00 0
React. x x x
Equilibrium 1.00-x 2.00-x x
The Kc has following equation:
Kc = [HCONH2]/([CO]*[NH3])
Using our values:
Kc = x/((1-x)*(2-x))
or:
x/((1-x)*(2-x)) = 0.640
x/(2-3x+x2) = 0.640
x = 0.640x2 - 1.92x + 1.28
0.640x2 - 2.92x + 1.28 = 0
where
x = 0.491
So the equilubrium concentrarion of HCONH2 equals 0.491 M
Answer: [HCONH2]eq = 0.491 M.
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