Using Ideal Gas law, "PV=nRT \\implies n=PV\/RT"
"P=23psi= 23*0.068046 atm"
"V= 500 ml = 0.5 L"
"T=23^o C= 273+23=296 K"
"R= 0.0821 Latmmol^{-1}K^{-1}"
"\\implies n = 23*0.068046*0.5\/(0.0821*296)= 0.0322 mol"
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