By Graham's Law of Diffusion,
Rate of diffusion is inversely proportional to the square root of the molar mass of gas.
r∝1Mr\propto\frac{1}{\sqrt{M}}r∝M1
MO2=32 g,MN2=28 g.M_{O_2}=32 \ g,M_{N_2}=28\ g.MO2=32 g,MN2=28 g.
⟹ rN2rO2=MO2MN2=3228=1.069=1.07\implies \frac{r_{N_2}}{r_{O_2}}=\sqrt{\frac{M_{O_2}}{M_{N_2}}}=\sqrt{\frac{32}{28}}=1.069=1.07⟹rO2rN2=MN2MO2=2832=1.069=1.07 (up to 333 significant digits)
⟹ \implies⟹ rN2=1.07×rO2r_{N_2}=1.07\times r_{O_2}rN2=1.07×rO2 .
So,Nitrogen gas is 1.071.071.07 times faster than oxygen gas.
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