CaCO3 + 2 HNO3 = Ca(NO3)2 + CO2 + H2O
There were 20 g/100 g/mole = 0.2 mole of CaCO3 and equimolar amount of CO2 evolved.
CO2 gas volume evolved at STP is 0.2 mole*22.4 L/mole = 4.48 L
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