Question #104611
A solution contains a mixture of pentane and hexane at room temperature. The solution has a vapor pressure of 240 torr . Pure pentane and hexane have vapor pressures of 425 torr and 151 torr, respectively, at room temperature.
What is the mole fraction of hexane? (Assume ideal behavior.)
1
Expert's answer
2020-03-05T07:57:17-0500

vapour pressure=Phexoχhex+Ppenoχpenvapour\ pressure =P^o_{hex}*\chi_{hex}+P^o_{pen}*\chi_{pen}

Vapour pressure=151χhex+425χpenVapour \ pressure = 151*\chi_{hex}+425*\chi_{pen}

240=151χhep+425(1χhep)240=151*\chi_{hep}+425*(1-\chi_{hep})

(425151)χhep=425240χhep=185/274=0.675(425-151)\chi_{hep}=425-240 \newline \chi_{hep}=185/274= 0.675


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