Question #67636

An electron is confined to a one-dimensional region in which its ground-state (n = 1) energy is 2.00 eV. (a) What is the length of the region? (b) How much energy is required to promote the electron to its first excited state?
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Expert's answer

2017-04-27T14:47:07-0400

Answer on Question #67636, Physics / Atomic and Nuclear Physics

An electron is confined to a one-dimensional region in which its ground-state (n=1)(n = 1) energy is 2.00 eV. (a) What is the length of the region? (b) How much energy is required to promote the electron to its first excited state?

Find: a?ΔE?a - ?\Delta E - ?

Given:

n1=1n_1 = 1

n2=2n_2 = 2

E1=2.00eV=2.00×1.6×1019JE_{1} = 2.00\mathrm{eV} = 2.00\times 1.6\times 10^{-19}\mathrm{J}

m=9.10×1031kg\mathrm{m = 9.10\times 10^{-31}kg}

h=6.63×1034J×sh = 6.63 \times 10^{-34} \, \text{J} \times s

Solution:

Energy of electron:

En=h28a2mn2\mathrm{E_n = \frac{h^2}{8a^2m}n^2} (1)

Of (1) \Rightarrow a = h2n128Em\sqrt{\frac{h^2n_1^2}{8Em}} (2)

Of (2) \Rightarrow a=0.4×10-9m

Of (1) \Rightarrow ΔE=h28a2m(n22n12)\Delta E = \frac{h^2}{8a^2m} (n_2^2 - n_1^2) (3)

Of (3) \Rightarrow ΔE=11.32×1019J\Delta E = 11.32 \times 10^{-19} \, \text{J}

1 eV - 1.6×10-19 J

ΔE11.32×1019J\Delta E - 11.32 \times 10^{-19} \, \text{J}

ΔE=7eV\Delta E = 7 \, \text{eV}

Answer:

(a) 0.4×109m0.4 \times 10^{-9} \, \text{m}

(b) 7eV7 \mathrm{eV}

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